Phosphorylation of Alkenyl and Aryl C-O Bonds via Photoredox/Nickel Dual Catalysis
A phosphorylation of alkenyl and aryl C-O bonds at room temperature via photoredox/nickel dual catalysis is reported. By starting from easily available and inexpensive sulfonates, a variety of important alkenyl phosphonates and aryl phosphine oxides are g
A general method is described for the formation of vinylphosphines from arylsulfonylhydrazones.Oxidation of the resulting vinylphosphines yields phosphine oxides.
Mislankar, Dattatraya G.,Mugrage, Ben,Darling, S. D.
p. 4619 - 4622
(2007/10/02)
CARBON-PHOSPHORUS HETEROCYCLES. BIOLOGICAL ACTIVITY OF CERTAIN C-P HETEROCYCLES AND THE SYNTHESIS OF 4b,5,6,10b,11,12-HEXAHYDRO-5,5-DIPHENYLBENZOPHOSPHANTHRIDINIUM HEXAFLUOROPHOSPHATE
A total synthesis of the carbon-phosphorus (C-P) heterocycle 4b,5,6,10b,11,12-hexahydro-5,5-diphenylbenzophosphanthridinium hexafluorophosphate is recorded.
Radhakrishna, A. S.,Berlin, K. Darrell,Helm, Dick van der
p. 495 - 502
(2007/10/02)
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