764-95-4Relevant articles and documents
Nucleophilic addition to acetylenes in superbasic catalytic systems: X. Catalytic effect of alkali metal hydroxides in the vinylation of 1-heptanol
Parshina,Oparina,Gorelova,Preiss,Henkelmann,Trofimov
, p. 940 - 945 (2001)
- The catalytic activity of alkali metal hydroxides in base-catalyzed addition of 1-heptanol to acetylene depends on the alkali metal nature and degree of hydration of its hydroxide. In a closed system, the catalytic activity of alkali metal hydroxides decreases in the series 2KOH·H2O > RbOH·H2O > CsOH·H2O > NaOH. The corresponding series for a flow system is as follows: RbOH·H2O > CsOH·H2O > 2KOH·H2O > NaON > KOH·H2O. The difference is explained by participation of the catalyst in side reactions with both 1-heptanol and acetylene. Addition of dimethyl sulfoxide to the catalytic system accelerates the vinylation process.
Nucleophilic addition to acetylenes in superbasic catalytic systems: XIII. Fluoride cesium containing systems, efficient catalysts for alkanols vinylation
Oparina,Shaikhudinova,Parshina,Vysotskaya,Preiss,Henkelmann,Trofimov
, p. 656 - 660 (2007/10/03)
New catalytic systems CsF-MOH (M = Li, Na) were developed for the synthesis of alkyl vinyl ethers comparable in efficiency to cesium alcoholates. The addition of primary and secondary alcohols to acetylene occurs in the presence of these systems at the atmospheric (DMSO, 100°C) or at enhanced (without solvent, 135-140°C) acetylene pressure and affords alkyl vinyl ethers in up to 93% yield. 2005 Pleiades Publishing, Inc.
Nucleophilic addition to acetylenes in superbasic catalytic systems: XI. Transformations of alkali metal hydroxides during vinylation of 1-heptanol with acetylene under elevated pressure
Oparina,Parshina,Khil'ko,Gorelova,Preiss,Henkelmann,Trofimov
, p. 1553 - 1558 (2007/10/03)
Base-catalyzed addition of 1-heptanol to acetylene under elevated pressure of the latter is accompanied by side processes including formation of carboxylic acid salts (alkali metal heptanoates and acetates) with liberation of hydrogen and acetylene polyme
Acetals containing acetylenic groups and their surface activity in the system LiN(SO2CF3)2-tetraglyme
Ivanova,Gorkovenko,Gusarova,Oparina,Skotheim,Trofimov
, p. 117 - 120 (2007/10/03)
Acetals exhibiting surface activity in the system LiN(SO2CF3)2-MeO(CH2CH2O)4Me can be prepared in a quantitative yield by electrophilic addition of acetylenic alcohols to vinyl heptyl ether