- Chiral benzyl centers through asymmetric catalysis. A three-step synthesis of (R)-(-)-α-curcumene via asymmetric hydrovinylation
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(Chemical Equation Presented) A three-step, two-pot procedure involving asymmetric hydrovinylation followed by Suzuki-Miyaura reaction represents by far the shortest synthesis of this popular bisabolane. Other applications for the synthesis of similar com
- Zhang, Aibin,RajanBabu
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- Concise asymmetric total syntheses of (?)-nuciferol, (?)-nuciferal, and (?)-dihydrocurcumene via Rh(I)-catalyzed boronic acid addition
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A general catalytic asymmetric total synthesis of aromatic bisabolane sesquiterpenes, (?)-nuciferol (ent-1c), (?)-nuciferal (ent-1d), and (?)-dihydrocurcumene (ent-1h) have been achieved in 5–6 steps in high chemical yields from commercially available (E)
- Pal, Souvik,Khatua, Arindam,Das, Mrinal K.,Bisai, Vishnumaya
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- Total synthesis of (R)- and (S)-turmerone and (7S,9R)-bisacumol by an efficient chemoenzymatic approach
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An enantioselective synthesis of (R)-, (S)-turmerone and (7S,9R)-bisacumol is described. The enantiomerically pure key intermediates, a substituted butanoate ester and acid are utilized in the synthesis of both enantiomers of turmerone. The lipase catalyzed resolution studies of the acetate of bisacumol have been exploited towards the total synthesis of the naturally occurring cytotoxic sesquiterpene, (7S,9R)-bisacumol with high diastereoselectivity (94% de).
- Kamal, Ahmed,Shaheer Malik,Azeeza, Shaik,Bajee, Shaik,Shaik, Ahmad Ali
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experimental part
p. 1267 - 1271
(2009/10/17)
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