Synthesis of Trichoverrin B and Its Conversion to Verrucarin J
Anguidine (3b) was converted to verrucarol (3a), which in turn was selectively acylated to yield trichoverin B (2).Trichoverrin B reacts with pyridinium dichromate in dimethylformamide, via a novel oxidative ring closure, to give verrucarin J (11a) in 50 percent yield.
Esmond, Robert,Fraser-Reid, Bert,Jarvis, Bruce B.
p. 3358 - 3360
(2007/10/02)
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