A General Synthesis of Ring-Fused Mesoionic Thiazolines from 2,2-Dicyanooxiranes under Neutral Conditions
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Baudy-Floc'h, M.,Robert, A.
p. 981 - 983
(2007/10/02)
OBTENTION D'INTERMEDIAIRES TETRAHEDRIQUES. AU COURS DE LA REACTION DES GEM DICYANOEPOXYDES AVEC LES THIOAMIDES SUBSTITUES. EVOLUTION DE CES INTERMEDIAIRES EN THIAZOLES MESOIONIQUES.
A tetrahedral intermediate is isolated from the reaction of gem dicyanoepoxyde with 2-mercapto 1-methyl imidazole, the breakdown of this compound leads to a mesoionic imidazothiazole through a ketene intermediate.
Baudy, M.,Robert, A.
p. 2517 - 2520
(2007/10/02)
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