Slight structural modulation around a pivotal bond: high impact on enantiomeric stability
Based on aN-arylthiazoline scaffold, 22 structures with a N-Carylchiral axis were synthesized exhibiting a huge molecular diversity for the four flanking substituents around the pivotal bond. The determination of their corresponding rotational
Albalat, Muriel,Belot, Vincent,Bossa, Giulia,Farran, Daniel,Jean, Marion,Roussel, Christian,Vanthuyne, Nicolas
p. 16039 - 16047
(2021/09/22)
Comparison of Racemization Processes in 1-Arylpyrimidine-2-thione and 3-Arylthiazoline-2-thione Atropisomers and Their Oxygen Analogues
1-(2'-Methylphenyl)-4,6-dimethylpyrimidine-2-thione (1a), its oxygen analogue (1b) and a series of N-aryl-4-methylthiazoline-2-thiones 2a-5a and -2-ones analogues 2b-5b have been separated into atropisomers by liquid chromatography on CSP microcrystalline
Synthesis and Mercuration of Some New 3-Aryl-4-substituted-2-thio-δ4-thiazolines as Pesticides
Some new 3-aryl-4-substituted-2-thio-Δ4-thiazolines (I) and their acetoxymercuri derivatives (II) have been synthesised.Both the types of compounds exhibit fungicidal activity against Pyricularia oryzae (Cav.) and bactericidal activity against Staphy. aureus and Esch. coli.
Dash, Manjula,Pattnayak, J.,Nath, J. P.,Mahapatra, G. N.
p. 918 - 920
(2007/10/02)
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