774547-41-0

Basic information

• Product Name: N-(4-bromobenzyl)-N-hexylamine
• Synonyms: N-(4-bromobenzyl)-N-hexylamine
• CAS NO: 774547-41-0
• Molecular Formula: C13H20BrN
• Molecular Weight: 270.2086
• Mol File: 774547-41-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-(4-bromobenzyl)-N-hexylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-bromobenzyl)-N-hexylamine(774547-41-0)
• EPA Substance Registry System: N-(4-bromobenzyl)-N-hexylamine(774547-41-0)

Safety Data

• Hazardous Substances Data: 774547-41-0(Hazardous Substances Data)

Upstream product

• 589-15-1 1-bromomethyl-4-bromobenzene 
• 109-05-7 2-Methylpiperidin 
• 29180-45-8 1-(4-bromobenzyl)-2-methylpiperidine 
• 766-08-5 methylphenylsilane 

Relevant articles and documents

Cine-Silylative Ring-Opening of α-Methyl Azacycles Enabled by the Silylium-Induced C-N Bond Cleavage

Described herein is the development of a borane-catalyzed cine-silylative ring-opening of α-methyl azacycles. This transformation involves four-step cascade processes: (i) exo-dehydrogenation of alicyclic amine, (ii) hydrosilylation of the resultant enamine, (iii) silylium-induced cis-β-amino elimination to open the ring skeleton, and (iv) hydrosilylation of the terminal olefin. The present borane catalysis also works efficiently for the C-N bond cleavage of acyclic tertiary amines. On the basis of experimental and computational studies, the silicon atom was elucidated to play a pivotal role in the β-amino elimination step.