REACTION OF SUPEROXO Co(III) COMPLEXES WITH 2,6-DI-t-BUTYL-p-BENZOQUINONE METHIDES
Superoxo Co(III) complexes derived from Co(Salpr) and (3-) reacted with 2,6-di-t-butyl-p-benzoquinone methides to give 2,6-di-t-butyl-p-benzoquinone and 2,6-di-t-butyl-2,5-cyclohexadienonespirooxiranes as the main products, which are considered to result from nucleophilic attack by superoxo species on the exo double bond of the quinone methides.
Nishinaga, A.,Tomita, H.,Tarumi, Y.,Matsuura, T.
p. 4849 - 4852
(2007/10/02)
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