77855-73-3Relevant articles and documents
1-[N-phenyl(aminomethyl)]silatrane: Synthesis, reactivity and structure
Lazareva,Sterkhova
, (2019)
1-[N-Phenyl(aminomethyl)]silatrane PhNHCH2Si(OCH2CH2)3N was prepared and characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffraction analysis. Its reactivity with CCl4, AgNOsu
METHOD FOR PRODUCING AMINOORGANOSILANES
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Page/Page column 8, (2012/04/04)
The invention relates to a method (a) for producing aminoorganyltriorganylsilanes of the general formula (1) R′3-nR1nSi—R2—NR3R4 (1), a method (b) for producing cyclic aminosilanes of the general formula (4), and a method (III) for producing silylorganoamines of the general formula (7) R013-tR11tSi—R12—NR13—R14—SiR023-sR15s (7), wherein amines are reacted with halogen organylsilanes, wherein R′, R1, R2, R3, R4, R, R5, R6, R01, R02, R11, R12, R13, R14, R15, n, and s have the meanings specified in claims 1 to 3, wherein after the reaction, the ammonium halides of the amines produced as by-products are released by adding a base (B) to the reaction mixture, the amines are removed from the reaction mixture by distillation, two liquid phases are formed by further adding base (B) to the reaction mixture, wherein the one phase contains at least 90 wt % of the hydrohalide of the base (B) and said phase is separated.
METHOD FOR PRODUCING AMINO-ORGANOSILANES
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Page/Page column 6, (2011/07/29)
In the preparation of aminoorganylsilanes and cyclic aminosilanes by reaction of an organyl amine with a haloorganylsilane, the byproduct halide salt of the amine reactant is decomposed to amine by addition of a base whose halide salt forms a liquid phase at a temperature below 200° C., and the liquid base halide is separated from the reaction mixture.
METHOD FOR THE PRODUCTION OF SILICON COMPOUNDS CARRYING AMINO GROUPS
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Page/Page column 15, (2008/06/13)
The invention relates to a method for producing (N-organylaminoorganyl)triorganylsilanes and (N,N-diorganylaminoorganyl)triorganylsilanes from corresponding (triorganylsilylorganyl)halides and N-organylamines or N,N-diorganylamines. Also disclosed are (N-