- New syntheses of 5,6- and 7,8-diaminoquinolines
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The synthesis of 5,6- and 7,8-diaminoquinoline derivatives starting from angularly annelated selenadiazoloquinolones is presented. Simple chlorination of the pyridone ring followed by reductive deselenation of the 1,2,5-selenadiazole ring afforded novel 4
- Bella, Maros,Milata, Viktor
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- Controlling ground and excited state properties through ligand changes in ruthenium polypyridyl complexes
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The capture and storage of solar energy requires chromophores that absorb light throughout the solar spectrum. We report here the synthesis, characterization, electrochemical, and photophysical properties of a series of Ru(II) polypyridyl complexes of the type [Ru(bpy)2(N-N)]2+ (bpy = 2,2-bipyridine; N-N is a bidentate polypyridyl ligand). In this series, the nature of the N-N ligand was altered, either through increased conjugation or incorporation of noncoordinating heteroatoms, as a way to use ligand electronic properties to tune redox potentials, absorption spectra, emission spectra, and excited state energies and lifetimes. Electrochemical measurements show that lowering the φ* orbitals on the N-N ligand results in more positive Ru3+/2+ redox potentials and more positive first ligand-based reduction potentials. The metal-to-ligand charge transfer absorptions of all of the new complexes are mostly red-shifted compared to Ru(bpy)32+ (λmax = 449 nm) with the lowest energy MLCT absorption appearing at λmax = 564 nm. Emission energies decrease from λmax = 650 nm to 885 nm across the series. One-mode Franck-Condon analysis of room-temperature emission spectra are used to calculate key excited state properties, including excited state redox potentials. The impacts of ligand changes on visible light absorption, excited state reduction potentials, and Ru3+/2+ potentials are assessed in the context of preparing low energy light absorbers for application in dye-sensitized photoelectrosynthesis cells.
- Ashford, Dennis L.,Glasson, Christopher R. K.,Norris, Michael R.,Concepcion, Javier J.,Keinan, Shahar,Brennaman, M. Kyle,Templeton, Joseph L.,Meyer, Thomas J.
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p. 5637 - 5646
(2014/06/23)
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- ALKALINE HYDROLYSIS OF 2-(TRIFLUOROMETHYL)IMIDAZO AND -QUINOLINES
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2-(Trifluoromethyl)imidazo and -quinoline have been prepared from 5(6)-acetamido-2-(trifluoromethyl)benzimidazole and 7,8-diaminoquinoline respectively.These (trifluoromethyl)quinolines like 2-(trifluoromethyl)imidazoles but unlike 2-(trifluoromethyl)benzimidazoles, undergo hydrolysis in dilute sodium hydroxide to give ultimately the corresponding imidazo and -quinoline, respectively.
- Moores, Ian G.,Smalley, Robert K.,Suschitzky, Hans
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p. 573 - 580
(2007/10/02)
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