Einfuehrung von Sauerstoff-Funktionen in die α-Stellung von β-Diketonen, 5. Acyloxylierung von 3-prim.-Amino-2-cyclohexen-1-onen
The enaminone 1 reacts with diacyl peroxides 2 to yield monoacyloxylation products 4 and (acylamino)cyclohexadienolones 6 which may be regarded as reaction products of an acyl rearrangement of the non-isolable bis-acyloxylation products 5.Catalytic hydrogenation of benzyl esters 4e and 6e obtained by the described way leads immediately to the amino reductone 8.
Schank, Kurt,Adler, Manfred
p. 2019 - 2028
(2007/10/02)
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