- Assessing the adsorption selectivity of linker functionalized, moisture-stable metal-organic framework thin films by means of an environment-controlled quartz crystal microbalance
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The stepwise thin film deposition of the robust, hydrophobic [Zn 4O(dmcapz)3]n (dmcapz = 3,5-dimethyl-4-carboxy- pyrazolato) is reported. The adsorption of small organic probe molecules, including alkanols, toluene, aniline and xylenes, was monitored by an environment-controlled quartz crystal microbalance setup. The adsorption selectivity was tuned by introducing alkyl side chains in the dmcapz linker.
- Betard, Angelique,Wannapaiboon, Suttipong,Fischer, Roland A.
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supporting information
p. 10493 - 10495,3
(2012/12/12)
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- Assessing the adsorption selectivity of linker functionalized, moisture-stable metal-organic framework thin films by means of an environment-controlled quartz crystal microbalance
-
The stepwise thin film deposition of the robust, hydrophobic [Zn 4O(dmcapz)3]n (dmcapz = 3,5-dimethyl-4-carboxy- pyrazolato) is reported. The adsorption of small organic probe molecules, including alkanols, toluene, aniline and xylenes, was monitored by an environment-controlled quartz crystal microbalance setup. The adsorption selectivity was tuned by introducing alkyl side chains in the dmcapz linker.
- Betard, Angelique,Wannapaiboon, Suttipong,Fischer, Roland A.
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supporting information
p. 10493 - 10495
(2013/01/15)
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- Procedures for the Acylation of Diethyl Malonate and Ethyl Acetoacetate with Acid Chlorides Using Tertiary Amine Bases and Magnesium Chloride
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In the presence of magnesium chloride and 2 equiv of triethylamine, diethyl malonate is C-acylated in excellent yields by acid chlorides.A variety of other metal chlorides were ineffective.Similarly, ethyl acetoacetate is C-acylated by acid chlorides in the presence of magnesium chloride and 2 equiv of pyridine.
- Rathke, Michael W.,Cowan, Patrick J.
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p. 2622 - 2624
(2007/10/02)
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