79458-27-8Relevant articles and documents
Selective, cofactor-mediated catalytic oxidation of alkanethiols in a self-assembled cage host
Da Camara, Bryce,Dietz, Philip C.,Chalek, Kevin R.,Mueller, Leonard J.,Hooley, Richard J.
supporting information, p. 14263 - 14266 (2020/11/24)
A spacious Fe(ii)-iminopyridine self-assembled cage complex can catalyze the oxidative dimerization of alkanethiols, with air as stoichiometric oxidant. The reaction is aided by selective molecular recognition of the reactants, and the active catalyst is derived from the Fe(ii) centers that provide the structural vertices of the host. The host is even capable of size-selective oxidation and can discriminate between alkanethiols of identical reactivity, based solely on size. This journal is
3,6-Di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) mediated metal-free mild oxidation of thiols to disulfides in aqueous medium
Samanta, Suvendu,Ray, Shounak,Ghosh, Abhisek Brata,Biswas, Papu
, p. 39356 - 39363 (2016/06/01)
Thiols are efficiently oxidized to disulfides (RSSR) in the presence of 3,6-di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) in aqueous medium, as well as in the absence of a solvent under mild and metal-free conditions. A broad range of alkyl, aryl and heterocyclic symmetrical disulfides can be easily obtained in almost quantitative yields. The X-ray single crystal structure of 2-aminocyclopent-1-ene-1-carbothioic dithioperoxyanhydride (disulfide obtained from 2-aminocyclopentene-1-dithiocarboxylic acid, ACDA) is reported. The reaction mechanism has been studied thoroughly. It is shown that the reaction proceeds through the formation of an organosulphur radical. Pytz interacts with thiol to accept one electron and produces an organosulphur radical. Pytz ultimately accepts two electrons to form H2pytz and is capable of oxidizing 2 equivalents of thiols.
Preparation, structures, and physical properties of tetrakis(alkylthio) tetraselenafulvalene (TTCn-TSeF, n = 1-15)
Saito, Gunzi,Yoshida, Yukihiro,Murofushi, Hidenobu,Iwasawa, Naoko,Hiramatsu, Takaaki,Otsuka, Akihiro,Yamochi, Hideki,Isa, Kimio,Mineo-Ota, Eriko,Konno, Michiko,Mori, Takehiko,Imaeda, Ken-Ichi,Inokuchi, Hiroo
supporting information; experimental part, p. 335 - 344 (2010/07/09)
A series of tetrakis(alkylthio)tetraselenafulvalene compounds (TTC n-TSeF, n = 1-15) were prepared by a one-step reaction between dialkyl disulfide and tetralithiated TSeF. Molecular properties (redox potentials and optical absorptions in solution) and solid-state properties (thermal behaviors, electric conductivities, and molecular and crystal structures for n = 1 and 10) were studied. TTCn-TSeF compounds are weak electron donor molecules and characterized by small on-site Coulomb repulsion. TTC1-TSeF has a high-dimensional conduction network owing to the presence of highdimensional heteroatomic contacts, "Atomic-Wire Effect." The π-moieties of TTC10-TSeF were fastened by the alkyl chains ("Fastener Effect") to form π-columns and there are a variety of short heteroatomic contacts resulting in two dimensional electronic structure. Electrical conductivity exhibited peculiar enhancement for n = 1 and 7 ≤ n ≤ 14 owing to the presence of high-dimensional conduction paths. These compounds may manifest high carrier mobility, and are good candidates for the field-effect transistor channel based on the advantageous features: low dark conductivity, low donor ability, on-site Coulomb repulsion energy, high-dimensional π-electron structure, and high solubility in organic solvents.
Oxidative transformation of thiols to disulfides promoted by activated carbon-air system
Hayashi, Masahiko,Okunaga, Ken-Ichi,Nishida, Shunsuke,Kawamura, Kenjiro,Eda, Kazuo
supporting information; experimental part, p. 6734 - 6736 (2011/02/25)
Efficient oxidative transformation of thiols to disulfides took place in the presence of activated carbon under an oxygen (or air) atmosphere. The present oxidation method is available not only for a variety of thiols such as simple aromatic and aliphatic thiols but also for 3,4-dihydropyrimidin-2(1H)- thiones and N-Boc-l-cysteine.
Method for preparing aromatic diphenyl thioethers
-
, (2008/06/13)
The invention concerns a method for preparing aromatic diphenyl thioethers. More particularly the invention concerns the preparation of 4-chloro-4′-thiomethyldiphenylether. The inventive method for preparing an aromatic diphenyl thioether is characterised in that it consists in reacting in an aqueous medium a diazonium salt of an aromatic diphenyl compound with a disulphide sulphur compound, in the presence of an efficient amount of a coupling catalyst.
Preparation and characterization of long-chain di-n-alkyl disulfides
Steinfatt, Ingeborg,Hoffmann, Gerhard G.,Brouwer, Ludwig,Menzel, Frank,Brockner, Wolfgang
, p. 31 - 55 (2007/10/03)
The preparation of long-chain symmetric di-n-alkyl disulfides based on the reaction of BUNTE SALTS (RS2O3Na) with iodine is reported. 1H-NMR, FT-IR, and FT-RAMAN spectra of the solid and liquid/molten aliphatic title disulfides were recorded. An assignment of the vibrational frequencies is proposed especially in regard to the S-S and C-S vibrations. Distinct spectral differences are determined between the solid and liquid state, as well as between disulfides with even and those with odd numbered alkyl substituents, respectively. The observed phenomena are ascribed to different species in the solids and liquids/melts and their respective VAN DER WAALS interactions. In addition, mass spectra, GC-MS studies, as well as the thermal behaviour of the disulfides, based on investigations by DSC and TGA, are reported.
Novel method for preparation of symmetric disulfides from thiols using enzyme catalysis
Sridhar,Kumara Vadivel,Bhalerao
, p. 1499 - 1502 (2007/10/03)
Mild and efficient method for preparation of variety of symmetric disulfides from oxidation of thiols using horseradish peroxidase or mushroom tyrosinase as catalyst is described.
An efficient and mild cleavage of thiol acetate with clayfen in the absence of solvent
Meshram, Harshadas M.
, p. 2521 - 2522 (2007/10/02)
The disulphides are synthesised through the mild cleavage of thiol acetate with clayfen in the absence of solvent.
