- Skeletal scrambling of sulphur diimide radical anions
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In the presence of a catalytic quantity of alkali metal mixtures of sulphur diimides RNSNR and R'NSNR' (R, R' = Ph, 4-C6H4Me, 4-C6H4OMe, SiMe3, SPh) undergo a rapid scrambling of the R and R' groups.When R and R' are significantly different (e.g., R = Ph,
- Bestari, Ketut,Oakley, Richard T.,Cordes, A. Wallace
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- Sulfur-Nitrogen-Compounds, VIII. Synthesis and Characterization of Some Aromatic Sulfurdiimines
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The missing compounds of the series of sulfurdiimines R1-N=S=N-R2 with R1/2 = C6H5, C6F5, C6H5S, C6F5S were prepared, and all ten compounds investigated.Thermal stability, UV/VIS-, IR- and 19F-NMR-spectra depend strongly on the combination of the substitu
- Brands, Gilbert,Golloch, Alfred
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p. 551 - 555
(2007/10/02)
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