Towards triptycene functionalization and triptycene-linked porphyrin arrays
Herein, 9,10-diethynyltriptycene is investigated for its use as a rigid isolating unit in the synthesis of multichromophoric arrays. Sonogashira cross-coupling conditions are utilized to attach various porphyrins and boron dipyrromethenes (BODIPYs) to the
Flanagan, Keith J.,Locke, Gemma M.,Senge, Mathias O.
DIAMINES, POLYIMIDES, METHODS OF MAKING EACH, AND METHODS OF USE
Aspects of the present disclosure provide for bridgehead-substituted triptycene-based diamines and methods of making bridgehead-substituted triptycene-based diamines.