REACTION OF 1,3-DIENES WITH ARYLSULFONYL THIOCYANATES
At room temperature arylsulfonyl thiocyanates add to conjugated dienes with the formation of 1,4-addition products.In all cases the organic sulfonyl radical is fixed at the least substituted carbon atom of the 1,3-diene system.In reaction with triethylamine or sodium ethoxide the adducts which form eliminate thiocyanic acid with the formation of conjugated dienyl sulfones.
Tanaskov, M. M.,Starodub, P. E.,Stadnichuk, M. L.,Tanaskova, E. A.
p. 1609 - 1615
(2007/10/02)
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