- Reaction of Hydrogen Peroxide with Organosilanes under Chemical Vapour Deposition Conditions
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When a stream of vapour at low pressure which contained a mixture of H2O2 with an organosilane, RSiH3 (R = alkyl or alkenyl), impinged on a silicon wafer, deposition of oxide films of nominal composition RxSiO(2-0.5x), where x 3 or higher alkenyl groups. or higher alkenylgroups. Possible mechanism for the Si-C bond cleavage reaction are discussed, with energetic rearrangement of radical intermediates of type Si(H)(R)(OOH)' being favoured.
- Moore, Darren L.,Taylor, Mark P.,Timms, Peter L.
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p. 2673 - 2678
(2007/10/03)
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- Synthesis of Cyclobutyl- and Cyclopentylsilane
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The reaction of iodosilane with cyclobutyl- or cyclopentylmagnesium bromide yielded cyclobutyl- (3) and cyclopentylsilane (4), respectively.Like cyclopropylsilane these new compounds show no reaction with oxygen or with water.
- Dakkouri, Marwan,Kehrer, Hermann
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p. 3460 - 3461
(2007/10/02)
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