32. 2'-Nitro-2'-propen-1'-yl 2,2-Dimethylpropanoate (NPP), A Multiple Coupling Reagent
The title compound 1 (NPP) is prepared from formaldehyde, nitromethane, and pivaloyl chloride.It is shown to be a versatile nitroallylating reagent combining with nucleophiles as different as anilines, indoles, enolates, and organolithium compounds.This i
Seebach, Dieter,Knocherl, Paul
p. 261 - 283
(2007/10/02)
NITROALLYLATION OF HIGHLY REACTIVE ORGANOLITHIUM COMPOUNDS BY 2-NITRO-3-PIVALOYLOXI-1-PROPENE (NPP)
The nitroolefin 1 (NPP) efficiently transfers a 2-nitroallyl group even to the most reactive nucleophilic centres of organolithium reagents to give the products of type 2 listed in the table.
Knochel, Paul,Seebach, Dieter
p. 3223 - 3226
(2007/10/02)
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