Reactions of Alkanoyl Fluorides with F-Isopropyl and F-1-Chloroethyl Anions
Reactions between alkanoyl chlorides and F-propene or F-chloroethene with fluoride ion were investigated.While alkyl (F-isopropyl) ketones and 1-(F-isopropyl)alkenol esters were formed in the former case, 1-(F-1-chloroethyl)alkenol esters were exclusively obtained in the latter case.Reaction mechanisms are discussed.
α-FLUOROALKYLAMINES - A NEW SOURCE OF THE UNHYDRATED FLUORIDE ION. 4. ACYLATION OF PERFLUOROALKYL CARBANIONS WITH THE FLUOROANHYDRIDES OF CARBOXYLIC ACIDS
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Igumnov, S. M.,Delyagina, N. I.,Knunyants, I. L.
p. 1924 - 1927
(2007/10/02)
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