Stepwise formation of triosmium edge double-bridged μ-H,μ-O=C(Nu) decacarbonyl complexes, Nu = NRR′, OR, or R. Reversal of barrier heights in the fluxional behavior of the anions [Ru3(μ-O=CNMe2)(μ-CO)3(CO) 7]- and [Os3(μ-O=CNMe2)(CO)10]- [6]
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Mayr,Lin,Boag,Kaesz
p. 1704 - 1706
(2008/10/08)
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