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DPEPO, with steric ortho-substituted diphenylphosphine oxide (DPPO) groups, is one of the most popular large band-gap materials used to host blue TADF-based OLEDs.

808142-23-6

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808142-23-6 Usage

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Bis[2-((oxo)diphenylphosphino)phenyl]ether (CAS# 808142-23-6), also known as DPEPO, is a fluorescent compound often incorporated into OLED materials.

Check Digit Verification of cas no

The CAS Registry Mumber 808142-23-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,0,8,1,4 and 2 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 808142-23:
(8*8)+(7*0)+(6*8)+(5*1)+(4*4)+(3*2)+(2*2)+(1*3)=146
146 % 10 = 6
So 808142-23-6 is a valid CAS Registry Number.

808142-23-6 Well-known Company Product Price

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  • TCI America

  • (B5240)  Bis[2-[(oxo)diphenylphosphino]phenyl] Ether  >97.0%(HPLC)

  • 808142-23-6

  • 1g

  • 990.00CNY

  • Detail

808142-23-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name Bis[2-((oxo)diphenylphosphino)phenyl] ether

1.2 Other means of identification

Product number -
Other names DPEPO

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:808142-23-6 SDS

808142-23-6Relevant articles and documents

Remarkable luminescence properties of lanthanide complexes with asymmetric dodecahedron structures

Miyata, Kohei,Nakagawa, Tetsuya,Kawakami, Ryuhei,Kita, Yuki,Sugimoto, Katsufumi,Nakashima, Takuya,Harada, Takashi,Kawai, Tsuyoshi,Hasegawa, Yasuchika

, p. 521 - 528 (2011)

The distorted coordination structures and luminescence properties of novel lanthanide complexes with oxo-linked bidentate phosphane oxide ligands-4,5-bis(diphenylphosphoryl)-9,9-dimethylxanthene (xantpo), 4,5-bis(di-tert-butylphosphoryl)-9,9-dimethylxanth

Eu COMPLEX AND ORGANIC EL ELEMENT

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Paragraph 0086; 0087, (2018/04/20)

PROBLEM TO BE SOLVED: To provide a particulate rare earth complex composition that enables thin film deposition in a solution process, and also enables light emission even when used as a light emitting layer of an organic EL device, and an organic EL devi

Photoluminescent tetrazolate-based Eu(III) complexes: An outstanding impact of aromatic phosphine oxide co-ligands on the photoluminescence quantum yields

Pietraszkiewicz, Marek,Mal, Suraj,Pietraszkiewicz, Oksana,Gorski, Krzysztof,Chelwani, Nitin

, p. 239 - 247 (2014/06/23)

New ternary Eu(III) 5-(2-pyridyl-1-oxide)tetrazolate complexes with phosphine oxide co-ligands have been synthesized and characterized by elemental analysis, and IR and 1H NMR spectroscopic techniques. The analytical data revealed that these complexes are

Convergent modulation of singlet and triplet excited states of phosphine-oxide hosts through the management of molecular structure and functional-group linkages for low-voltage-driven electrophosphorescence

Han, Chunmiao,Zhang, Zhensong,Xu, Hui,Xie, Guohua,Li, Jing,Zhao, Yi,Deng, Zhaopeng,Liu, Shiyong,Yan, Pengfei

, p. 141 - 154 (2013/03/13)

The controllable tuning of the excited states in a series of phosphine-oxide hosts (DPExPOCzn) was realized through introducing carbazolyl and diphenylphosphine-oxide (DPPO) moieties to adjust the frontier molecular orbitals, molecular rigidity, and the location of the triplet excited states by suppressing the intramolecular interplay of the combined multi-insulating and meso linkage. On increasing the number of substituents, simultaneous lowering of the first singlet energy levels (S1) and raising of the first triplet energy levels (T1, about 3.0 eV) were achieved. The former change was mainly due to the contribution of the carbazolyl group to the HOMOs and the extended conjugation. The latter change was due to an enhanced molecular rigidity and the shift of the T1 states from the diphenylether group to the carbazolyl moieties. This kind of convergent modulation of excited states not only facilitates the exothermic energy transfer to the dopants in phosphorescent organic light-emitting diodes (PHOLEDs), but also realizes the fine-tuning of electrical properties to achieve the balanced carrier injection and transportation in the emitting layers. As the result, the favorable performance of blue-light-emitting PHOLEDs was demonstrated, including much-lower driving voltages of 2.6 V for onset and 3.0 V at 100 cd m -2, as well as a remarkably improved E.Q.E. of 12.6 %.

RARE-EARTH COMPLEX AND USES THEREOF

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Page/Page column 16, (2012/07/14)

The rare-earth complex of the present invention has high luminous efficiency, since it has a structure represented by the following general formula (I):

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