Anodic Oxidation. Part 17. The Formation of Alkyl Methyl Carbonates in the Hofer-Moest Reaction in Methanol
The liquid products from the electrolysis of sodium butanoate in methanol containing methyl sodium carbonate at a graphite anode include propyl and 1-methylethyl methyl carbonates. 1,1-Dimethylethyl methyl carbonate is amongst the liquid products from the electrolysis of sodium 2,2-dimethylpropanoate in methanol at a platinum anode in the presence or absence of methyl sodium carbonate.Typical secondary products derived from propene or 2-methylpropene are also present in the liquid products from each of these electrolyses.
Brettle, Roger,Khan, M. Akhram,Rowbottom, John D.
p. 2927 - 2929
(2007/10/02)
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