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812-15-7

Articles about 812-15-7Total 3 be found

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FORMATION AND REACTIONS OF DIMETHYLSILYLENE AND DIMETHYLGERMYLENE
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Nefedov, O. M.,Skell, Philip S.
p. 320 - 322
(2007/10/02)

Evidence for the Isomerization of 1-Methylsilene to Dimethylsilylene
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Conlin, Robert T.,Wood, David L.
p. 1843 - 1844
(2007/10/02)

GAS-PHASE PHOTOCHEMICAL REACTIONS OF DODECAMETHYLCYCLOHEXASILANE WITH SILICON COMPOUNDS. KINETICS OF SOME INSERTION REACTIONS OF DIMETHYLSILYLENE
Attempts to measure the kinetics of gas-phase insertion reactions of dimethylsilylene, generated by photolysis of dodecamethylcyclohexasilane, are described.Insertion of dimethylsilylene into silicon-hydrogen bonds was the main reaction with trimethylsilane, pentamethyldisilane, and sym-tetramethyldisilane; in all cases the activation energy for insertion was zero, and the rate constants were in the ratio of 1:3.1:4.3.Dimethylsilylene also inserted cleanly into hydrogen chloride with an activation energy of 28 kJ mol-1.Photochemical reactions with methylchlorosilanes were much more complex, involving little or no silylene chemistry; such reactions as did occur appeared to proceed almost entirely by radical mechanisms.
Davidson, Iain M.T.,Ostah, Naaman A.
p. 149 - 158
(2007/10/02)

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Chemical Properties

Boiling Point: 99.6 °C at 760 mmHg
Flash Point:14 °C
Density: 0.722 g/mL at 25 °C(lit.)
Vapor Pressure: 43.8mmHg at 25°C
Refractive Index: n20/D 1.4240(lit.)
PSA: 0.00000
LogP: 1.88970

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