SPONTANEOUS -SIGMATROPIC REARRANGEMENT OF S-ARYLTHIOSULFONIUM YLIDS FORMED IN THE REACTION OF ARYLSULFENYL CHLORIDES WITH METHYLTHIOMETHYLTRIMETHYLSILANE
A new -sigmatropic rearrangement of thiosulfonium ylids yields ortho-methylthiomethylthiophenols.The ylids were generated through the cleavage of a C-Si bond with chloride anion.
Gassman, Paul G.,Miura, Takashi
p. 4787 - 4790
(2007/10/02)
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