ACID-CATALYZED RERRANGEMENT OF N-(1-METHYL-2-BUTENYL)ANILINE
The effect of the nature of the solvents and catalysts on the rerrangement of N-(1-methyl-2-butenyl)aniline was studied..The reaction is catalyzed by the hydrochlorides of aromatic amines and by Lewis acids.The nature of the solvents has an insignificant effect on the course of the rearrangement.
Abdrakhmanov, I.B.,Sharafutdidov, V.M.,Tolstikov, G.A.
p. 562 - 564
(2007/10/02)
AMINO-CLAISEN REARRANGEMENT AS A METHOD FOR THE SYNTHESIS OF C-SUBSTITUTED ANILINES
Various C-alkenylanilines were synthesized by an amino-Claisen rearrangement.The composition of the rearrangement products is affected by the nature of the substituents in the benzene ring and at the nitrogen atom of the initial anilines.
Abdrakhmanov, I. B.,Sharafutdinov, V. M.,Nigmatullin, N. G.,Sagitdinov, I. A.,Tolstikov, G. A.
p. 1278 - 1283
(2007/10/02)
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