KETOVINYLIERUNG VON THIOCARBONAMIDEN UND THIOHARNSTOFFEN. ZUR AMBIDENZ DER THIOAMIDFUNKTION
Thiocarbamides and thioureas 1 react as ambident systems with β-chlorovinyl ketones 2 to give the S--salts 3-5.Those obtained from monoprotic 1 undergo deprotonation, yielding isolable S-thioimidateesters or -isothioureas 6 r
Spitzner, R.,Mielke, D.,Scholz, D.,Schroth, W.,Preiss, A.
p. 927 - 936
(2007/10/02)
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