- Synthesis of 4-Alkyl-4H-1,2,4-triazole Derivatives by Suzuki Cross-Coupling Reactions and Their Luminescence Properties
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New derivatives of 4-alkyl-3,5-diaryl-4H-1,2,4-triazole were synthesized utilizing the Suzuki cross-coupling reaction. The presented methodology comprises of the preparation of bromine-containing 4-alkyl-4H-1,2,4-triazoles and their coupling with different commercially available boronic acids in the presence of ionic liquids or in conventional solvents. The obtained compounds were tested for their luminescence properties.
- Olesiejuk, Monika,Kudelko, Agnieszka,Swiatkowski, Marcin,Kruszynski, Rafal
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Read Online
- Fluorescent probes and application thereof to detection of neurotoxic agents
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The invention relates to fluorescent probes represented by a general formula I or II which is described in the specification, and application of the fluorescent probes in detection of neurotoxic agents. The fluorescent probes can be used for efficiently d
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Paragraph 0038; 0042-0044
(2020/05/01)
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- Polyamine monomer of polyimide containing triazole structure and polymer and preparation method of polyamine monomer as well as application
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The invention discloses a polyamine monomer of polyimide containing a triazole structure and a polymer and a preparation method of the polyamine monomer as well as application, and belongs to the fields of hyperbranched polyimide preparation technology an
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Paragraph 0062; 0063; 0066
(2019/08/06)
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- Diamine monomer of polyimide containing triazole structure and polymer, preparation method and application thereof
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The invention discloses a polyimide monomer with a triazole structure and a polymer,preparation method and application thereof, and belongs to the fields of polyimide preparation technology and information storage materials. The method comprises the follo
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Paragraph 0043; 0045; 0047
(2019/07/16)
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- Triazole and pyridine hybrid molecules as electron-transport materials for highly efficient green phosphorescent organic light-emitting diodes
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A series of triazole and pyridine hybrid molecules, with a triazole core and pyridine periphery, were designed and synthesized as an electron-transport layer (ETL) and a hole/exciton-block layer for green phosphorescent organic light-emitting diodes. Compared with the widely-used electron-transport material (ETM) of 3-(biphenyl-4-yl)-5-(4-tert-butylphenyl)-4-phenyl-4H-1,2,4-triazole (TAZ) with a triazole core, lower-lying HOMO and LUMO energy levels were obtained with the introduction of pyridine rings onto the periphery of the molecules, giving improved electron injection and carrier confinement. Significantly reduced driving voltages were achieved in a device structure of ITO/HATCN (5 nm)/TAPC (40 nm)/CBP:8 wt % Ir(PPy)3 (10 nm)/ETL (40 nm)/LiF (1 nm)/Al (90 nm), giving a maximum power efficiency of 72.2 lm W -1 and an external quantum efficiency of 21.8 %, due to the improved electron injection and transport and thus, more balanced carrier recombination, which are much higher than those of the device based on TAZ.
- Li, Xiang-Long,Ye, Hua,Chen, Dong-Cheng,Liu, Kun-Kun,Xie, Gao-Zhan,Wang, Yi-Fan,Lo, Chang-Cheng,Lien,Peng, Junbiao,Cao, Yong,Su, Shi-Jian
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p. 971 - 978
(2014/08/18)
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- Bipolar material with spiro-fluorenyl terminals: Synthesis, characterization and application for enhancement of electrophosphorescence
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We have designed a novel bipolar material (FTzCz) consisting of spiro-fluorenyl terminals and a bipolar core to enhance emission efficiency of phosphorescent light-emitting diodes based on a conventional poly(9-vinylcarbazole) host and Ir(ppy)3
- Wu, Chia-Shing,Wu, Juin-Wei,Chen, Yun
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supporting information
p. 23877 - 23884
(2013/01/15)
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- Conjugated polymers containing electron-deficient main chains and electron-rich pendant groups: Synthesis and application to electroluminescence
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Two novel conjugated polymers denoted TAZF2 and TAZBTF, having electron-deficient main chains and electron-rich triphenylamine pendant groups, were designed and synthesized. While TAZF2 was constructed with fluorene and electron-deficient 1,2,4-triazole a
- Wang, Kun-Li,Leung, Man-Kit,Hsieh, Li-Ga,Chang, Chin-Chuan,Lee, Kueir-Rarn,Wu, Chun-Lung,Jiang, Jyh-Chiang,Tseng, Chieh-Yu,Wang, Hui-Tang
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scheme or table
p. 1048 - 1062
(2012/03/27)
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- Synthesis of n-type π-conjugated polymers with pendant crown ether and their stability of n-doping state against air
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The n-type π-conjugated polymers with a 1,2,4-triazole ring substituted by a benzo-15-crown-5-ether (benzo15C5) subunit at the 4-position of the 1,2,4-triazole ring were synthesized by organometallic polycondensations. The UV-vis spectra of the polymers e
- Yamaguchi, Isao,Mitsuno, Hidehito
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scheme or table
p. 9348 - 9354
(2011/11/29)
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- Poly(p-phenylenevinylene) derivatives containing electron-transporting aromatic triazole or oxadiazole segments
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We report the synthesis, optical and electrochemical details, and properties of copolymers P1-P3 consisting of alternate hole-transporting 1,4-bis(hexyloxy)-2,5-distyrylbenzene (HDB) and electron-transporting 4-(4-(hexyloxy)phenyl)-3,5-diphenyl- 4H-1,2,4-
- Chen, Shinn-Horng,Chen, Yun
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