Rapid solution and solid phase synthesis of monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5-thiopheneethynylene)]s
Monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5-thiopheneethynylene)] s, new candidates for molecular wires, were rapidly synthesized via an iterative divergent/convergent doubling strategy in solution as well as on Merrifield's resin.
Synthesis of monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5- thiopheneethynylene)]s
The synthesis of monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5- thioph-eneethynylene)]s using an iterative divergent/convergent doubling strategy based on Sonogashira coupling reaction was presented.
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[[3-butyl-5-[[4-[[3-butyl-5-[(4-iodophenyl)ethynyl]-2-thienyl]ethynyl]phenyl]
ethynyl]-2-thienyl]ethynyl]trimethyl-