Kinetics and Mechanism of the Aminolysis of Phenyl Thionoacetate in Aqueous Solution
The reactions of a series of secondary alicyclic amines with the title substrate have been subjected to a kinetic study in water at 25 deg C, ionic strength 0.2 M.Pseudo-first-order rate coefficients (kobsd) are found throughout, under amine ex
Castro, Enrique A.,Ibanez, Fernando,Santos, Jose G.,Ureta, Carmen
p. 4908 - 4912
(2007/10/02)
Reduction of Thionoesters to Ethers by Triorganotin Hydrides
Esters 1 are efficiently deoxygenated to the corresponding ethers 3 in two steps by first conversion to the thionoesters 2 and subsequent reduction of these by triorganotin hydrides.
Smith, Colin,Tunstad, Linda M.,Gutierrez, Carlos G.
p. 257 - 260
(2007/10/02)
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