HIGHLY EFFICIENT SYNTHESIS OF ALPHA-O-GALACTOSYL CERAMIDES
A method for the production of a-O-galactosyl ceramide precursor is demonstrated. The method involves the reaction of galactosyl iodide with a sphingosine derivative or phytosphingosine derivative in the presence of a quaternary ammonium iodide salt to pr
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Page/Page column 14; 16
(2008/06/13)
Efficient synthesis of α-galactosyl ceramide analogues using glycosyl iodide donors
(Chemical Equation Presented) The combination of reactive galactosyl iodide donors with electron-rich acceptor lipids provides highly stereoselective and efficient routes to α GalCer analogues. Using per-O-silylated donors, key intermediates can be obtain
Du, Wenjun,Gervay-Hague, Jacquelyn
p. 2063 - 2065
(2007/10/03)
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