Chemically synthesized and cross-linked PDMS as versatile alignment medium for organic compounds
A useful procedure for the preparation of chemically synthesized and cross-linked polydimethylsiloxane (PDMS) gels is presented, which does not require β-irradiation for cross-linking. NMR spectra of high quality are obtained, such that even mixtures of compounds exhibiting similar NMR spectra like interconverting stereoisomers can be investigated in the residual dipolar coupling (RDC) approach of organic structure determination.
Moskalenko, Yulia E.,Bagutski, Viktor,Thiele, Christina M.
supporting information
p. 95 - 98
(2016/12/27)
ENANTIOSELECTIVITY IN THE HYDROLYSIS OF BICYCLIC MONOTERPENE ACETATES WITH THE CULTURED CELLS OF NICOTIANA TABACUM
Key Word Index - Nicotiana tabacum; Solanaceae; tissue culture; biotransformation; hydrolysis; enantioselectivity; bicyclic monoterpene acetates.The enantioselectivity in the hydrolysis of bornyl acetate; isobornyl acetate and isopinocampheyl acetate with the cultured cells of Nicotiana tabacum was investigated.The cultured cells were found to have the ability to hydrolyse enantioselectively the acetates, of which the configuration at the carbon atom bearing the acetoxyl group is R.
Suga, Takayuki,Hirata, Toshifumi,Izumi, Shunsuke
p. 2791 - 2792
(2007/10/02)
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