Sequential Ene Reactions. A New Annelation Procedure
Alkylidenecycloalkanes 1 undergo two sequential Me2AlCl-catalyzed ene reactions with α,β-unsaturated carbonyl compounds to give bicyclic alcohols 3.At low temperatures, the initial ene adducts 2 can be isolated when vinyl ketones are used.This reaction ha
Snider, Barry B.,Deutsch, Ethan A.
p. 1822 - 1829
(2007/10/02)
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