858956-08-8

Basic information

• Product Name: 6-AMINO-5-CHLORO-2-CYCLOPROPYLPYRIMIDINE-4-CARBOXYLIC ACID
• Synonyms: 6-AMINO-5-CHLORO-2-CYCLOPROPYLPYRIMIDINE-4-CARBOXYLIC ACID;6-Amino-5-chloro-2-cyclopropyl-4-pyrimidinecarboxylic acid;Aminocyclopyrachlor;Aminocyclopyrachlor [iso];DPX-MAT 28
• CAS NO: 858956-08-8
• Molecular Formula: C8H8ClN3O2
• Molecular Weight: 213.62102
• EINECS: 1312995-182-4
• Mol File: 858956-08-8.mol

Chemical Properties

• Boiling Point: 432.3°C at 760 mmHg
• Flash Point: 215.3°C
• Appearance: /
• Density: 1.635g/cm³
• Vapor Pressure: 3.06E-08mmHg at 25°C
• Refractive Index: 1.7
• Storage Temp.: Keep in dark place,Sealed in dry,Store in freezer, under -20°C
• Solubility: DMSO (Slightly), Methanol (Slightly)
• PKA: 7.04±0.10(Predicted)
• CAS DataBase Reference: 6-AMINO-5-CHLORO-2-CYCLOPROPYLPYRIMIDINE-4-CARBOXYLIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 6-AMINO-5-CHLORO-2-CYCLOPROPYLPYRIMIDINE-4-CARBOXYLIC ACID(858956-08-8)
• EPA Substance Registry System: 6-AMINO-5-CHLORO-2-CYCLOPROPYLPYRIMIDINE-4-CARBOXYLIC ACID(858956-08-8)

Safety Data

• Statements: 52/53
• Safety Statements: 61
• RIDADR: UN3077 (solid); UN3082 (liquid)
• Hazardous Substances Data: 858956-08-8(Hazardous Substances Data)

Usage

Trade name

IMPRELlIS?; Ortho MAT28; SG Herbicide; DPX-MAT28; VIEWPOINT HERBICIDE; STREAMLINE HERBICIDE; WEED & FEED

InChI:InChI=1/C8H8ClN3O2/c9-4-5(8(13)14)11-7(3-1-2-3)12-6(4)10/h3H,1-2H2,(H,13,14)(H2,10,11,12)

Downstream Products

• 858954-83-3 methyl 6-amino-5-chloro-2-cyclopropyl-4-pyrimidinecarboxylate 

Relevant articles and documents

Fatty Amine Salts Of Herbicidal Pyrimidines

This invention is directed to (1) a soluble intermediate prepared from reaction of the acid form of one or more of the compounds disclosed by Formula I given below with at least one long-chain fatty amine; (2) a process for solubilizing one or more of the compounds disclosed by Formula I given below by reacting said compounds with at least one long-chain fatty amine to form a fatty-amine salt of Formula I compound; and (3) a finished pesticide product comprising at least one of the soluble intermediates, that is, fatty-amine salt of Formula I compound. wherein R1 is cyclopropyl optionally substituted with 1-5 R5, isopropyl optionally substituted with 1-5 R6, or phenyl optionally substituted with 1-3 R7;R2 is ((O)jC(R15)(R16))kR;R is CO2H or a herbicidally effective derivative of CO2H;R3 is halogen, cyano, nitro, OR20, SR21 or N(R22)R23;R4 is —N(R24)R25 or —NO2;j is 0 or 1; and k is 0 or 1; provided that when k is 0, then j is 0; and R5, R6, R7, R15, R16, R20, R21, R22, R23, R24 and R25 are as defined in the disclosure.

METHOD FOR PREPARATION OF OPTIONALLY 2-SUBSTITUTED 1,6-DIHYDRO-6-OXO-4-PYRIMIDINECARBOXYLIC ACIDS

A new method for the preparation of optionally 2-substituted 1,6-dihydro-6-oxo-4 pyrimidinecarboxylic acid compounds of formula (1) is disclosed wherein R1 is H or an optionally substituted carbon moiety. Also disclosed is the method comprising additional steps to prepare optionally substituted 4 pyrimidine-carboxylic acids and esters using the compound of formula (1) as an intermediate.

HERBICIDAL PYRIMIDINES

Compounds of Formula I, and their N-oxides and agriculturally suitable salts, are disclosed which are useful for controlling undesired vegetation wherein R1 is cyclopropyl optionally substituted with 1-5 R5, isopropyl optionally subs