Asymmetric Lewis acid mediated [1,2]-rearrangement of proline-derived ammonium ylides
The first example of asymmetric Lewis acid mediated [1,2]-rearrangement of N-benzylic proline amides to form quaternary proline derivatives is reported. The presented reaction is shown to proceed with remarkable high C→N→C chirality transfer. Various quat
Tuzina, Pavel,Somfai, Peter
supporting information; experimental part
p. 919 - 921
(2009/08/15)
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