Stereoselective synthesis of α-C-glucosyl serine and alanine via a cross-metathesis/cyclization strategy
(Chemical Equation Presented) C-Glycosyl amino acids represent stable mimics of monomeric units within natural O-linked glycoproteins. Olefin cross-metathesis has been used to provide alkene precursors for a mercury(II)-mediated cyclization, yielding α-C-
Nolen, Ernest G.,Kurish, Adam J.,Potter, Jennifer M.,Donahue, Lawrence A.,Orlando, Michael D.
p. 3383 - 3386
(2007/10/03)
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