Ferrocenyl compounds possessing protected phenol and thiophenol groups: Synthesis, X-ray structure, and in vitro biological effects against breast cancer
We have previously shown that conjugated ferrocenyl p-phenols show strong cytotoxic effects against both the hormone-dependent MCF-7 and hormone-independent MDA-MB-231 breast cancer cell lines, possibly via metabolic quinone methide (QM) formation. To fur
Heilmann, Julia B.,Hillard, Elizabeth A.,Plamont, Marie-Aude,Pigeon, Pascal,Bolte, Michael,Jaouen, Gérard,Vessières, Anne
p. 1716 - 1722
(2008/09/18)
Utilization of microwave heating in the McMurry reaction for facile coupling of aldehydes and ketones to give alkenes
Microwave heating was applied in high-yield syntheses of alkenes by McMurry coupling of aldehydes and ketones with low-valent titanium. All aldehydes and ketones including sulfur end-capped analogues gave alkenes in isolated yields above 80% without detectable amounts of pinacols.
Stuhr-Hansen, Nicolai
p. 5491 - 5494
(2007/10/03)
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