- Reaction of 3,4-Bis(ethoxycarbonyl)-1,2,5-oxadiazole 2-Oxide with Olefins
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3,4-Bis(ethoxycarbonyl)-1,2,5-oxadiazole 2-oxide (1) has been shown to react with several olefins in a molar ratio of 1:2, giving 5-(ethoxycarbonyl)-1-aza-2,8-dioxabicyclooctanes (2).Evidence is presented that these products arise from 1,3-dipolar cycloaddition, elimination of ethyl cyanoformate from the initial cycloadducts, and 1,3-dipolar cycloaddition of the resulting isoxazoline N-oxides with another mole of olefin.
- Shimizu, Tomio,Hayashi, Yoshiyuki,Teramura, Kazuhiro
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p. 3053 - 3058
(2007/10/02)
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