Ultrafast Molecular Rotors and Their CO2 Tuning in MOFs with Rod-Like Ligands
A metal organic framework (MOF) engineered to contain in its scaffold rod-like struts featuring ultrafast molecular rotors showed extremely rapid 180 ° flip reorientation with rotational rates of 1011 Hz at 150 K. Crystal-pore accessibility of
Ultra-Fast Molecular Rotors within Porous Organic Cages
Using variable temperature 2H static NMR spectra and 13C spin-lattice relaxation times (T1), we show that two different porous organic cages with tubular architectures are ultra-fast molecular rotors. The central para-phen
Hughes, Ashlea R.,Brownbill, Nick J.,Lalek, Rachel C.,Briggs, Michael E.,Slater, Anna G.,Cooper, Andrew I.,Blanc, Frédéric
supporting information
p. 17217 - 17221
(2017/11/28)
Ionic rotors. Preparation, structure, and dynamic solid-state 2D NMR study of the 1,4-diethynylbenzenebis(triphenylborate) dianion
The reaction between p-(LiC2)2C6H4 (generated in situ from butyllithium and dialkynylbenzene) and 2 equiv of BPh3 affords high yields of [Li(THF)4]2[p-(Ph3BC2/su
Gardinier, James R.,Pellechia, Perry J.,Smith, Mark D.
p. 12448 - 12449
(2007/10/03)
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