- Reactions of Thionyl Chloride with Tetraorganotin(IV) Compounds
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The reactions of thionyl chloride with tetraorganotin(IV) derivatives (R4Sn where R = CH3, C2H5, n-C3H7, n-C4H9, C6H5CH2, C6H4CH3) bring about cleavage of tin-carbon bonds to give dialkyl/aryltin(IV) and alkyl/aryl sulphinyl chlorides.The ease of cleavage observed on the basis of the reactivities of R4Sn follows the order: n-C4H9 > n-C3H7 > C2H5 > CH3 > C6H5CH2 >> C6H4CH3.This order is not the same as commonly known in literature.
- Narula, Suraj P.,Sharma, R. K.,Lata, Sneh,Walia, Rita
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p. 246 - 247
(2007/10/02)
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