Synthesis Based on Cyclohexadienes. Part 15. Total Synthesis of (+/-)-Prezizaene, (+/-)-Prezizanol and (+/-)-Jinkohol II
A new methodology for the synthesis of the complex ring system tricyclo1,5>undecane, present in the zizaene group of sesquiterpenes, is described.Acid-catalysed rearrangement of the endo alcohol 20 afforded the enone 12, which was trans
Selvakumar, Natesan,Rao, G. S. R. Subba
p. 3217 - 3224
(2007/10/02)
(+)- Or (-)-7-hydroxymethyl-2,6,6-trimethyltricyclo[6,2,1,01,5 ]undecane
(+)- or (-)-7-hydroxymethyl-2,6,6-trimethyltricyclo[6,2,1,01,5 ]undecane represented by the following formula (I) or (II): STR1