Preparation of 1,4-hydrobenzoquinones by the PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2-diols
The PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2- diols, which were easily prepared by the two-step sequence of α-hydroxylation of various conjugated cyclohexenones and the subsequent nucleophilic carbonyl addition of alkyl anions, produced diversely substituted 1,4-hydrobenzoquinones. The Royal Society of Chemistry 2005.
Kim, Hee Jin,Koo, Sangho
p. 3479 - 3481
(2007/10/03)
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