Redox-Switched Crown Ethers. 1. Redox-Coupled Control of Metal-Ionophore Interactions and Their Application to Membrane Transport
Polyether ionophores with redox-functional thiol groups were synthesized: they are a diaza-18-crown-6 with a disulfide cap that exhibits redox-responsive interconversion between crown (1red) and cryptand (1ox) and tri- and tetra(oxye
REDOX-SWITCHED CROWN ETHERS. CROWN-CRYPTAND INTERCONVERSION COUPLED WITH REDOX OF THIOL GROUPS
A crown ether capped with a redox-functionalized thiol-disulfide couple was synthesized.The oxidized form with an ionophoric cap binds K+, Rb+, and Cs+ more efficiently than the reduced form with two lariattype groups.This
Shinkai, Seiji,Inuzuka, Kenichi,Manabe, Osamu
p. 747 - 750
(2007/10/02)
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