870152-14-0Relevant articles and documents
Gallium-Catalyzed Domino Arylation/Oxycyclization of Allenes with Phenols
Alcaide, Benito,Almendros, Pedro,Herrera, Fernando,Luna, Amparo,De Orbe, M. Elena,Torres, M. Rosario
, p. 4157 - 4163 (2015)
The synthesis of dihydrobenzofuran-appended oxindoles has been accomplished taking advantage of an unprecedented reaction between allenols and phenols under metal catalysis. (Chemical Equation Presented).
Metal-catalyzed rearrangements of 3-allenyl 3-hydroxyindolin-2-ones in the presence of halogenated reagents
Alcaide, Benito,Almendros, Pedro,Luna, Amparo,Prieto, Natividad
, p. 1216 - 1225 (2013)
The reactions of 3-allenyl 3-hydroxyoxindoles with a variety of halogenated reagents in the presence of catalytic amounts of precious metal salts were explored. Both, rearrangement and oxycyclization reactions to give 4-(1-halovinyl)-quinolinediones or spirocyclic halooxindoles, respectively, are competitive pathways. The kind of functionalization is substrate and reaction conditions dependent.
Palladium Nanoparticles in Water: A Reusable Catalytic System for the Cycloetherification or Benzannulation of α-Allenols
Alcaide, Benito,Almendros, Pedro,González, Ana M.,Luna, Amparo,Martínez-Ramírez, Sagrario
, p. 2000 - 2006 (2016/07/06)
A convenient ligand-free catalytic system has been developed for the chemoselective cyclization reaction of various α-allenol derivatives by palladium nanoparticles (PdNPs) in an aqueous reaction medium. (Figure presented.) .
An Alternative to Precious Metals: Hg(ClO4)2·3H2O as a Cheap and Water-Tolerant Catalyst for the Cycloisomerization of Allenols
Alcaide, Benito,Almendros, Pedro,Luna, Amparo,Soriano, Elena
supporting information, p. 7050 - 7057 (2015/07/28)
Hg(ClO4)2·3H2O, a cheap, water-tolerant, and stable salt, catalyzes the cycloisomerization reaction or α-allenols to 2,5-dihydrofurans in an efficient and selective manner. The reaction is general and can be applied to dif
Efficient entry to diversely functionalized spirocyclic oxindoles from isatins through carbonyl-addition/cyclization reaction sequences
Alcaide, Benito,Almendros, Pedro,Rodriguez-Acebes, Raquel
, p. 2346 - 2351 (2007/10/03)
A novel approach to diversely functionalized spirocyclic oxindoles has been developed by using different metal-mediated carbonyl-addition/cyclization reaction sequences. Spirocyclization precursors, 2-indolinonetethered homoallylic alcohols, (buta-1,3-die
Pd-Cu bimetallic catalyzed domino cyclization of α-allenols followed by a coupling reaction: New sequence leading to functionalized spirolactams
Alcaide, Benito,Almendros, Pedro,Rodriguez-Acebes, Raquel
, p. 5708 - 5712 (2007/10/03)
A novel regioselective metal-catalyzed spirocyclization of α-allenolscross coupling (Heck, Sonogashira, and Suzuki) reaction sequence, leading to potentially bioactive spirocyclic lactam derivatives has been developed. Precursors for the tandem spirocycli