Configurational Stability of the 2,2-Diphenyl-1-(trimethylsilyl)cyclopropyl Carbanion and Free Radical. Absolute Stereochemical Assigments to Select Silylcyclopropanes.
2,2-Diphenylcyclopropanecarboxylic acid was silylated at the 1-position and this product was resolved l-cinchonidine.The resulting optically active acid was transformed into (-)-2,2-diphenyl-1-methyl-1-(trimethylsilyl)cyclopropane, whose absolute configur
Paquette, Leo A.,Uchida, Takane,Gallucci, Judith C.
p. 335 - 340
(2007/10/02)
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