Synthesis of a 3-arylisoquinoline alkaloid, decumbenine B
The synthesis of a 3-arylisoquinoline alkaloid, decumbenine B, was accomplished in a reaction sequence based on the formation of an indolizine ring (dibenz[a,f]indolizin-5(7H)-one) followed by its cleavage at the amide bond, starting with an interaction o
3-Phenylisoquinolines from Phthalaldehyde and Phthalimidine
Phthalaldehyde (1) reacts with phthalimidine (3) via 5 and 6 to give the 3-phenylisoquinolines 7a and 7b.Acyliminium salts 12 are formed from the "carbinolamine" 6.
Dusemund, Juergen,Kroeger, Eckhard
p. 2 - 9
(2007/10/02)
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