890098-08-5

Basic information

• Product Name: 2-FLUORO-3'-METHOXYBENZOPHENONE
• Synonyms: 2-FLUORO-3'-METHOXYBENZOPHENONE;(2-fluorophenyl)-(3-methoxyphenyl)methanone
• CAS NO: 890098-08-5
• Molecular Formula: C14H11FO2
• Molecular Weight: 230.23
• Mol File: 890098-08-5.mol

Chemical Properties

• Boiling Point: 366.4°C at 760 mmHg
• Flash Point: 169.4°C
• Appearance: /
• Density: 1.176g/cm³
• Vapor Pressure: 1.47E-05mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: 2-FLUORO-3'-METHOXYBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-FLUORO-3'-METHOXYBENZOPHENONE(890098-08-5)
• EPA Substance Registry System: 2-FLUORO-3'-METHOXYBENZOPHENONE(890098-08-5)

Safety Data

• Hazardous Substances Data: 890098-08-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H11FO2/c1-17-11-6-4-5-10(9-11)14(16)12-7-2-3-8-13(12)15/h2-9H,1H3

Upstream product

• 766-85-8 3-methoxy-1-iodobenzene 
• 393-52-2 2-Fluorobenzoyl chloride 
• 2398-37-0 3-methoxyphenyl bromide 
• 446-52-6 2-Fluorobenzaldehyde 

Relevant articles and documents

Preparation of Functionalized Diorganomagnesium Reagents in Toluene via Bromine or Iodine/Magnesium-Exchange Reactions

A wide range of polyfunctionalized di(hetero)aryl- and dialkenyl-magnesium reagents are prepared in toluene within 10 to 120 minutes between 78 C and 25 C via an I/Mg- or Br/Mg-exchange reaction using reagents of the general formula R2Mg (R = sBu, Mes). Highly sensitive functional groups, such as triazene or nitro, are tolerated in these exchange reactions, enabling the synthesis of various functionalized (hetero)arene and alkene derivatives after quenching with several electrophiles including allyl bromides, acyl chlorides, aldehydes, ketones, and aryl iodides.

Elemental step thermodynamics of various analogues of indazolium alkaloids to obtaining hydride in acetonitrile

A series of analogues of indazolium alkaloids were designed and synthesized. The thermodynamic driving forces of the 6 elemental steps for the analogues of indazolium alkaloids to obtain hydride in acetonitrile were determined using an isothermal titration calorimeter (ITC) and electrochemical methods, respectively. The effects of molecular structure and substituents on the thermodynamic driving forces of the 6 steps were examined. Meanwhile, the oxidation mechanism of NADH coenzyme by indazolium alkaloids was examined using the chemical mimic method. The result shows that the oxidation of NADH coenzyme by indazolium alkaloids in vivo takes place by one-step concerted hydride transfer mechanism.