- Synthesis of all the stereoisomers of 6-methyl-2-octadecanone, 14-methyl-2-octadecanone, and 6,14-dimethyl-2-octadecanone, sex pheromone components of the Lyclene dharma dharma moth, from the enantiomers of citronellal
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The enantiomers of citronellal were converted to all the stereoisomers of 6-methyl-2-octadecanone, 14-methyl-2-octadecanone, and 6,14-dimethyl-2- octadecanone, the female-produced sex pheromone components of the Lyclene dharma dharma moth. Three wellestablished procedures, the Wittig reaction, alkylation of alkynes, and acetoacetic ester synthesis, were employed for the carbon-carbon bond formation to connect the building blocks.
- Shikichi, Yasumasa,Mori, Kenji
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p. 1943 - 1951
(2013/01/15)
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- Pheromone Synthesis, CXXV. Synthesis of the Four Possible Stereoisomers of 3,7-Dimethylnonadecane, the Female Sex Pheromone of Agromyza frontella Rondani
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The synthesis of the four possible stereoisomers of 3,7-dimethylnonadecane (1) has been achieved by starting from the enantiomers of methyl 3-hydroxy-2-methylpropanoate (2) and (R)-(+)-citronellic acid (3).
- Mori, Kenji,Wu, Jiang
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p. 213 - 217
(2007/10/02)
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- Synthesis of All of the Three Possible Stereoisomers of 13,23-Dimethylpentatriacontane, a Sex Pheromone of the Tsetse Fly, Glossina pallidipes
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The three possible stereoisomers of 13,23-dimethylpentatriacontane, a tsetse fly pheromone, were synthesized starting from optically pure (R)-(+)-citronellic acid. (13R,17R)-13,17-Dimethylpentatriacontane was also synthesized.
- Kuwahara, Shigefumi,Mori, Kenji
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p. 2599 - 2606
(2007/10/02)
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