The Mechanism of Benzophenone-sensitised Oxidation of 9-Phenilxanthene with Oxygen
From an investigation of the effect of inhibitors, quenchers, and the failure of a singlet sensitiser to effect the oxidation, it is proposed that the benzophenone-sensitised oxidation of 9-phenylxanthene with oxygen is a type I process.Further support for this conclusion is afforded by spectroscopic considerations.Evidence is also presented that the oxidation is a non-chain process, and the effect of acid on the product distribution is discussed.
Glover, Stephen A.,Goosen, Andre,McCleland, Cedric W.,Taljaard, Benjamin,Vogel, F. Ruric
p. 1205 - 1210
(2007/10/02)
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