A New Procedure for the One-Carbon Homologation of Ketones to α-Hydroxy Aldehydes
A new, one-carbon homologation procedure for the conversion of ketones to α-hydroxy aldehydes involves two steps: (1) Darzens condensation of ketones with chloromethyl phenyl sulfone; (2) ring opening of the intermediate α,β-epoxy sulfones with hydroxide
Adamczyk, Maciej,Dolence, E. Kurt,Watt, David S.,Christy, M. Robert,Reibenspies, Joseph H.,Anderson, Oren P.
p. 1378 - 1382
(2007/10/02)
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