Synthesis of (E)- and (Z)-Cyclopropyl-3-chloroalanine
Both stereoisomers of cyclopropyl-3-chloroalanine (1) were synthesized by diazomethane cyclopropanation of the appropiate oxazolones (2).X-ray crystallographic analysis elucidated the configurations of 1 and gave some insight into its possible conformational preferences.
Bland, John M.,Stammer, Charles H.,Varughese, Kottayil I.
p. 1634 - 1636
(2007/10/02)
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